000 01861nam a22002057a 4500
005 20231120152659.0
008 231120b ||||| |||| 00| 0 eng d
022 _a0021-9584
100 _aOnbey, Hilary
245 _aFeasibility of Using a Multicompartment Electrochemical Cell for Determination of Solubility Product Constants of Silver Salts from Potentiometric Measurements
_b : A Directed Study in the Undergraduate Physical Chemistry Laboratory (Journal Article)
260 _aWashington DC
_b :American Chemical Society
_c ,2023
300 _a2733-2738p.
440 _aJournal of Chemical Society
_v, Volume 100: Number 7, July 2023
505 _a***______{For Hard Copy, Please visit Library.}________***
520 _aAbstract: The use of a multicompartment electrochemical cell for the potentiometric determination of solubility product constants of aqueous I–, Br–, SCN–, and Cl– salts of silver is presented. An electrochemical cell presented in this study contained multiple half-cells made of disposable drinking straws, a silver wire electrode housed in a plastic syringe, and a reference electrode. An agreement between the solubility product constant values of AgI, AgBr, AgSCN, and AgCl obtained by the students (7.84 × 10–17, 4.34 × 10–13, 9.01 × 10–13, and 1.44 × 10–10) and the literature values (8.52 × 10–17, 5.35 × 10–13, 1.03 × 10–12, and 1.77 × 10–10, respectively) underscored the feasibility of using the cell for the determination of solubility product constants.
650 _aAnions| Electrochemical cells| Equilibrium constant| Salts| Silver| Analytical Chemistry| Physical Chemistry| Electrochemistry| Potentiometry
700 _aStringfellow, Kaitlin | Dabke, Rajeev B. | Gebeyehu, Zewdu | Melaku, Samuel
856 _uhttps://doi.org/10.1021/acs.jchemed.2c01251
942 _cPER
999 _c44969
_d44968