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Derivation of Dq/B and C/B from Electronic Spectra of Transition Metal Ions in Cubic Fields Using Auxiliary Tanabe–Sugano Diagrams (Journal Article)

By:

Verónica García Rojas and Jhon Fredy Pérez Torres

Material type: Text

TextSeries: American Chemical Society, Volume 100, Issue 1Publication details: Washington, United States :American Chemical Society ,January 10, 2023Description: 251-258 pISSN:

0021-9584

Subject(s):

DDC classification:

540.7

Online resources:

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Contents:

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Summary: Abstract- Auxiliary Tanabe–Sugano diagrams are presented. They enable a rapid and reliable graphical derivation of Dq/B and C/B crystal field parameter ratios from spectroscopic data. Using these values, one can calculate Dq and B by employing the original Tanabe–Sugano diagrams. Subsequently, C can also be calculated irrespective of the value C/B fixed in the Tanabe–Sugano diagram.

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Holdings
Item type	Current library	Call number	Status	Date due	Barcode
Periodicals	RIE BPL Library	540.7 (Browse shelf(Opens below))	Not for loan

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Abstract-

Auxiliary Tanabe–Sugano diagrams are presented. They enable a rapid and reliable graphical derivation of Dq/B and C/B crystal field parameter ratios from spectroscopic data. Using these values, one can calculate Dq and B by employing the original Tanabe–Sugano diagrams. Subsequently, C can also be calculated irrespective of the value C/B fixed in the Tanabe–Sugano diagram.

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Derivation of Dq/B and C/B from Electronic Spectra of Transition Metal Ions in Cubic Fields Using Auxiliary Tanabe–Sugano Diagrams (Journal Article)

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