Conversion of Adipic Acid to Bis-2-ethylhexyl Adipate Overcoming Equilibrium Constraints: A Laboratory Experiment (Record no. 44694)
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| fixed length control field | 01942nam a22002657a 4500 |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20231106101556.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 231030b ||||| |||| 00| 0 eng d |
| 022 ## - INTERNATIONAL STANDARD SERIAL NUMBER | |
| ISSN | 0021-9584 |
| 037 ## - SOURCE OF ACQUISITION | |
| Source of stock number/acquisition | RIEBPL Library |
| 082 ## - DEWEY DECIMAL CLASSIFICATION NUMBER | |
| Classification number | 540.7 |
| 100 ## - MAIN ENTRY--AUTHOR NAME | |
| Personal name | Domenico C. M. Albanese |
| 245 ## - TITLE STATEMENT | |
| Title | Conversion of Adipic Acid to Bis-2-ethylhexyl Adipate Overcoming Equilibrium Constraints: A Laboratory Experiment |
| Remainder of title | (Journal Article) |
| Statement of responsibility, etc | |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) | |
| Place of publication | Washington, United States |
| Name of publisher | :American Chemical Society |
| Year of publication | ,January 10, 2023 |
| 300 ## - PHYSICAL DESCRIPTION | |
| Number of Pages | 361-365p. |
| 490 ## - SERIES STATEMENT | |
| Series statement | American Chemical Society, Volume 100, Issue 1 |
| 505 ## - FORMATTED CONTENTS NOTE | |
| Formatted contents note | ***______{For Hard Copy, Please visit Library.}________*** |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc | Abstract:-<br/><br/>An adipic acid esterification experiment suitable for graduate students has been developed to describe the industrial manufacture of plasticizers. Students first follow the progress of the reaction with simple acid/base titration enabling measurement of the acid number. During the workup of the reaction mixture, they learn how to manage the filtration of a viscous mixture over an inert support such as Celite and practice on atmospheric and vacuum distillations. They finally learn to set a mass balance on 2-ethylhexanol using fully experimental data from their own reactions. To this end, they also learn how to retrieve from a 1H NMR spectrum the required data to evaluate the purity and the yield of bis-2-ethylhexyl adipate. These tasks corroborate basic concepts related to the tools available to shift the equilibrium in reversible reactions, at the same time providing new knowledge on mass balance calculations and 1H NMR.<br/><br/> |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Graduate Education/Research |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Laboratory Instruction |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Hands-On Learning/Manipulatives |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Industrial Chemistry |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Plasticizers Esterification |
| 856 ## - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | https://pubs.acs.org/doi/epdf/10.1021/acs.jchemed.2c00951 |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Koha item type | Periodicals |
| Lost status | Damaged status | Home library | Current library | Date acquired | Full call number | Koha item type |
|---|---|---|---|---|---|---|
| RIE BPL Library | RIE BPL Library | 06.11.2023 | 540.7 | Periodicals |